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From this table it is clear that the improved phenolic FR-4 materials are not quite as good in terms of electrical performance in the range of 2 5 GHz as the conventional dicy-cured materials, particularly with respect to Df. However, material E exhibits thermal properties at least as good if not better than even the improved materials discussed up to this point. In addition, the electrical performance of material E is even better than the conventional dicy-cured materials, especially in terms of Df performance. This non-dicy, non-phenolic material is an attractive material for use in applications requiring not only lead-free compatibility, but electrical performance superior to the phenolic materials that have been adopted in existing lead-free designs.

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While most base materials comply with the RoHS directive, the question of compatibility with lead-free assembly processes is a more complex issue. The material properties that are important for lead-free assembly compatibility include:

Decomposition temperature (Td) Coefficients of thermal expansion (CTEs)

Glass transition temperature (Tg) (especially because of the impact on thermal expansion) Moisture absorption Time-to-delamination performance, which is not a fundamental material property, but is a simple method used to assess thermal stability of a composite material at different temperatures

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While laminate manufacturers can easily make improvements in one of these properties, it is not as easy to make improvements without affecting other properties, including properties important for ease of manufacturing in the PCB fabrication process. Achieving the optimal balance of properties that consider the requirements of each level of the supply chain from OEM to EMS to PCB fabricator is crucial for success in lead-free assembly applications. Conventional dicy-cured FR-4 materials, especially the high-Tg dicy-cured materials, are significantly impacted by lead-free assembly temperatures, and are generally not recommended for lead-free applications. Alternative resin systems, especially the phenolic-cured FR-4 materials, have gained widespread acceptance in these applications, and where both thermal performance and electrical performance are critical, non-dicy, non-phenolic materials are also available. 11 discusses material selection in lead-free applications in more detail.

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{{11 Oct 09 Harprit Sandhu LCDTester.Spin Propeller Tool Ver. 1.2.6 Test program for LCD Routines }} CON _CLKMODE=XTAL1+ PLL2X _XINFREQ = 5_000_000 high =1 low =0 VAR byte index OBJ LCD : "LCDRoutines" UTIL : "Utilities" PUB Go LCD.initialize_lcd LCD.print (string("Initialized OK")) LCD.position(2,1) LCD.print (string("Print test")) UTIL.pause (1500) LCD.clear LCD.position (1,1) LCD.print (string("this is 1st line")) UTIL.pause (300) LCD.position(2,1) LCD.print (string("ok is on line 2")) UTIL.pause (1500) LCD.clear LCD.print (string("Position test")) UTIL.pause (1500) index:=0 repeat 16 index := index +1 LCD.clear LCD.position (1,index) LCD.print (string("X")) UTIL.pause (300)

1. Brist, Gary, Hall, Stephen, Clauser, Sidney, and Liang, Tao, Non-Classical Conductor Losses Due to Copper Foil Roughness and Treatment, ECWC 10/IPC/APEX Conference, February 2005. 2. Bergum, Erik, Application of Thermal Analysis Techniques to Determine Performance of Base Materials through Assembly, IPC Expo Technical Conference Proceedings, Spring 2003. 3. Kelley, Edward, An Assessment of the Impact of Lead-Free Assembly Processes on Base Material and PCB Reliability, IPC/Soldertec Conference, Amsterdam, June 2004. 4. Hoevel. Dr. Bernd, Resin Developments Targeting Lead-Free and Low Dk Requirements, EIPC Conference, 2005. 5. Christiansen, Walter, Shirrell, Dave, Aguirre, Beth, and Wilkins, Jeanine, Thermal Stability of Electrical Grade Laminates Based on Epoxy Resins, IPC Printed Circuits Expo, Anaheim, CA, Spring 2001. 6. Kelley, Ed, Bergum, Erik, Humby, David, Hornsby, Ron, Varnell, William, Lead-Free Assembly: Identifying Compatible Base Materials for Your Application, IPC/Apex Technical Conference, February 2006. 7. St. Cyr, Valerie A., New Laminates for High Reliability Printed Circuit Boards. Proceedings of IPC Technical Conference, February, 2006 8. Freda, Michael, and Furlong, Jason, Application of Reliability/Survival Statistics to Analyze Interconnect Stress Test Data to Make Life Predictions on Complex, Lead-Free Printed Circuit Assemblies, EPC 2004, October 2004. 9. Brist, Gary, and Long, Gary, Lead-Free Product Transition: Impact on Printed Circuit Board Design and Material Selection, ECWC 10/APEX/IPC Conference, February 2005. 10. Ehrler, Sylvia, Compatibility of Epoxy-Based PCBs to Lead-Free Assembly, EIPC Winter Conference, 2005, Circuitree, June 2005. 11. IST procedure developed and offered through PWB Interconnect Solutions, Inc., www.pwbcorp.com.

//loop through all the customer orders while (orders.hasNext()) { OrdersViewRowImpl currentOrder = (OrdersViewRowImpl)orders.next(); //if the order is open then apply the discount if (currentOrder.getOrderStatus().equals(OPEN_ORDER)) { //Get the current order total Number orderTotal = currentOrder.getOrderTotal(); //Deduct 50 off the total currentOrder.setOrderTotal((Number)orderTotal .minus(DISCOUNT)); } } } }

10 discussed the impact of lead-free assembly on printed circuit boards (PCBs) and base materials, and also discussed many of the critical base material properties relevant to performance in lead-free applications. These properties included:

Decomposition temperature (Td) Glass transition temperature (Tg) Coefficients of thermal expansion (CTEs) Moisture absorption Time to delamination, such as T260 and T288 tests

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