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Materials such as this have not performed with adequate reliability to be considered for anything but the simplest lead-free applications In addition, if PCBs made with these materials are stored in uncontrolled environments and are allowed to absorb even a modest level of moisture, the combination of lower Td s with the higher vapor pressure of water at lead-free temperatures can lead to catastrophic defects in assembly or severely degraded long-term reliability To take this a step further, examine the materials listed in Table 103 These are four FR-4 materials, with material C being the same material as shown if Fig 104, and material D being.

100 300.81 C 97.96% Weight (%)

297.83 C 297.02 C 98.96% 304.33 C 94.98%

{{Position cursor }} PUB POSITION (LINE_NUMBER, HOR_POSITION) | CHAR_LOCATION 'Pos the crsr 'Horizontal Position : 1 to 16 'specified by the two numbers 'Line Number : 1 or 2 CHAR_LOCATION := (LINE_NUMBER-1) * 64 'figr loc. See Hitachi data CHAR_LOCATION += (HOR_POSITION-1) + 128 'figr loc. See Hitachi data SEND_INSTRUCTION (CHAR_LOCATION) 'send the instr to pos crsr {{Check for busy }} PUB CHECK_BUSY | BUSY_BIT 'routine to check busy bit OUTA[ReadWrite] := 1 'Set to read the busy bit OUTA[RegSelect] := 0 'Set to read the busy bit DIRA[DataBit7..DataBit0] := %0000_0000 'Set to be an input REPEAT 'Keep doing it till clear OUTA[Enable] := 1 'set to 1 to toggle H>L this bit BUSY_BIT := INA[DataBit7] 'the busy bit is bit 7 of the byte read 'INA is the 32 input pins on the PROP and we 'are reading data bit 7 which is on pin 15! OUTA[Enable] := 0 'make the enable bit go low for H>L toggle WHILE (BUSY_BIT == 1) 'do it as long as the busy bit is 1 DIRA[DataBit7..DataBit0] := %1111_1111 'set back to outputs {{Print decimal }} PUB PRINT_DEC (VALUE) | TEST_VALUE'for printing values in decimal format IF (VALUE < 0) 'if it is a negative value -VALUE 'change it to a positive SEND_CHAR("-") 'and print a - sign on the LCD ' TEST_VALUE := 1_000_000_000 'we get indiv digits by comp to this 'value. div by 10 to get the nxt val REPEAT 10 'T 10 digits maximum in our system (continued)

FIGURE 10.4 Decomposition curve for a standard dicy-cured high-Tg FR-4.

the same as the material in Fig. 10.5. The impact of decomposition temperature when these materials are exposed to multiple thermal cycles to different peak temperatures is highlighted in Figs. 10.7 and 10.8. Figure 10.7 graphs cumulative weight loss (decomposition) for these materials when cycled repeatedly to a peak temperature of 235 C. Clearly, there is little impact on

329.29 C 326.48 C 99.03% 328.43 C 98.02% 330.37 C 94.99%

Weight (%)

program 21-10

FIGURE 10.5 Decomposition curve for a phenolic high-Tg FR-4.

Now generate the OrdersViewImpl class, ensuring that you choose to include bind variable accessors. You can then add the following code:

336.26 C 98.95%

391.10 C

366.57 C 98.02% 95 405.13 C 94.99%

Weight (%)

Usable LCD Methods in LCDRoutines (continued)

80 0

300 200 Temperature ( C)

resin decomposition when the peak temperature reaches 235 C. Figure 10.8 presents the same results when the peak temperature is increased to 260 C. The increase in temperature to 260 C has a severe impact on resin decomposition for the traditional FR-4 materials as they experience multiple thermal cycles, especially the conventional high-Tg material (product C). The rapid degradation in material C after only a few thermal cycles highlights why this material is not recommended for lead-free assembly applications. Indeed, as more data are gathered, thermal cycling seems to have a much greater impact than even one cycle to a very high temperature, even if the cycling occurs for a long time. As an example, review Fig. 10.9, which plots decomposition versus time at different isotherm temperatures for a standard dicycured high-Tg FR-4 material (C in Figs. 10.7 and 10.8). In Fig. 10.9 it can be seen that relatively low levels of decomposition are experienced for extended time periods even at the 260 C and 275 C isotherm temperatures. This same material, C in Fig. 10.8, exhibits rapid decomposition when cycled up to 260 C and cooled to room temperature multiple times.

public void changeOrderModeFilter(String mode) { ViewCriteria vc = getViewCriteria("OrdersModeViewCriteria"); setOrderModeBind(mode); applyViewCriteria(vc); executeQuery(); }