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In the case of these area-array devices, the high-lead content solder connection is an integral part of the package and not just a link between a component lead and bonding pad on a circuit board Further, these packages are generally used in high-end systems such as telecommunications equipment and powerful computers The RoHS legislation exempts such equipment from restrictions on Pb until 2010 In the meantime, package manufacturers are working to find and test reliable replacements for Pb-based solders for high-end packages Some smaller ICs have already made the switch to Pb-free interconnects Other exclusions or exemptions detailed in the current RoHS directive are Cd and Pb in batteries, Pb in video monitor screens, and Hg in fluorescent light bulbs.

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It is curious to note that RoHS legislation targets Pb in solders even though solder represents a minor use of Pb (it is estimated to comprise less than 10 percent of world Pb usage) Conversely, the exempted Pb-acid storage battery is the major consumer of Pb accounting for more than 85 percent worldwide Pb usage In August 2006, additional exemptions were allowed for the RoHS legislation As will be discussed in subsequent chapters, lead has been used to reduce or eliminate the occurrence of tin whiskers (metallic dendrites of tin that grow from pure tin surfaces) Metallic whiskers, such as from tin or zinc, are known to pose a reliability risk in terms of electrical shorting between oppositely charged conductors Therefore, the RoHS legislation has been amended to allow lead in surface finishes of components with pitch 065 mm for tin whisker repression.

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This applies to NiFe (Alloy 42, also known as Kovar) lead-frames as well as to components with copper lead-frames Curiously, the exemption does not cover connectors..

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Thermodynamic change in polymer from a relatively rigid, glassy state, to a softened, more deformable state. Rate of change in physical dimension (in x-, y-, or z-axis) as a function of temperature, expressed as a coefficient of thermal expansion. Can also be expressed as a percentage expansion over a given temperature range.

Tendency of a material to absorb moisture from the surrounding environment. Can be assessed by more than one method, including water soak or in an increased pressure and humidity environment.

Not a fundamental property; measurement of the time for delamination to occur at a specific temperature, e.g. 260 C (T260) or 288 C (T288).

TIp For a cancelled order, this code will prevent the update of all order attributes; however, the parameter index indicates which attribute is being checked, so you have the flexibility to decide which attributes are updateable and which are not.

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between Tg and thermal expansion requires further analysis. Figure 10.2 illustrates the relationship between Tg and thermal expansion for the products in Table 10.3. From Fig. 10.2, products with the same pre- and post-Tg CTE values (A and C, for example; note that above Tg the lines are parallel) differ in total expansion based on their Tg values. For example, the conventional 175 C Tg material (C) exhibits less total expansion than the conventional 140 C Tg material (A) because the onset of the higher post-Tg rate of expansion is delayed by 35 C. However, the 175 C material with a lower CTE value (D) exhibits much less total expansion than the conventional 175 C Tg material even though the Tg values are the same. Furthermore, the 150 C Tg material with reduced CTE values (B) exhibits approximately the same total expansion (3.4 percent) as the conventional 175 C Tg

material (3.5 percent). However, with a decomposition temperature that is significantly higher, this mid-Tg FR-4 material is much more compatible with lead-free assembly than the conventional 175 C Tg material. 10.5.2 The Importance of Decomposition Temperature Although glass transition temperature (Tg) and z-axis expansion have been a primary focus of attention over the years, only with the introduction of lead-free assembly has the decomposition temperature (Td) gained significant attention. The decomposition temperature has always been important in terms of reliability, yet most people have used Tg as a proxy for material reliability. One reason for this is that other things being equal, a higher-Tg results in less total thermal expansion, and therefore less stress on plated vias.What wasn t discussed is that it is common for conventional dicy-cured, high-Tg FR-4 materials to exhibit somewhat lower decomposition temperatures than conventional dicy-cured, 140 C Tg FR-4 materials. This is highlighted by the fact that most conventional 140 C Tg FR-4 materials exhibit longer T260 times than conventional high-Tg FR-4 materials. To highlight the importance of Td, examine Fig. 10.3. The traditional dicy-cured, high-Tg FR-4 materials we have become familiar with have Td values in the range of 290 310 C. Traditional 140 C Tg FR-4 materials are generally somewhat higher, with a typical example of a material with a Td of 320 C shown in Fig. 10.3. In the typical tin-lead assembly environment, peak temperatures do not reach the point where decomposition is significant for either the traditional or enhanced products. However, in the lead-free assembly environment, peak temperatures reach the point where a small but significant level of decomposition can occur for the conventional materials, but not for the enhanced products.

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