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Comparisons of dicy-cured materials with non-dicy cured materials, especially the phenolic FR-4 materials developed for lead-free assembly, show that the elimination of dicy can have a positive impact on CAF resistance. This may be due to reduced moisture absorption when dicy is removed, or to the elimination of an electrochemical reaction that may be promoted in the presence of dicy, or to both. Lead-free assembly can stress the resin-to-glass bond, and even cause some level of resin decomposition, which can create microvoids within a PCB. These phenomena can make it easier for pathways for CAF formation to be created. The use of more thermally stable resin systems may be required when CAF resistance is needed in products that will experience lead-free assembly.

Base material electrical properties are an important consideration in sophisticated printed circuits operating at high frequencies. High data rates, measured in gigabits per second (Gbps), and high clock speeds make the dielectric constant (Dk) and dissipation factor (Df) of base materials very important in high-speed digital circuits. Wireless and RF applications operating at very high frequencies also demand very low Dk and Df values. Moreover, the consistency of these properties over a large frequency range is also important. These properties were defined in Chap. 8 as follows:

Dielectric constant/permittivity This is the ratio of the capacitance of a capacitor with a given dielectric material to the capacitance of the same capacitor with air as a dielectric. It refers to the ability of a material to store an electric charge. Dissipation factor/loss tangent The property is the ratio of the total power loss in a material to the product of the voltage and current in a capacitor in which the material is a dielectric.

Importance of Dk and Df These properties are important because they affect signal transmission in the printed circuit. At low frequencies, a signal path in a printed circuit can typically be represented electrically as a capacitance in parallel with a resistance. However, as frequencies increase, at some point signal paths must be considered transmission lines where the electrical and dielectric properties of the base materials have a greater effect on signal transmission. A full discussion of capacitive versus transmission line environments is beyond the scope of this chapter, but the premise is to determine, for the transmission of a signal pulse of a given rise time, the acceptable length of a conductor before a significant voltage difference is realized along its length. Conductors longer than this critical value are then regarded as transmission lines. Because the velocity of signal propagation is inversely proportional to the square root of the permittivity of the dielectric, a lower permittivity value results in faster signal speeds and a longer rise distance. With a larger rise distance, larger conductor lengths are acceptable before a significant voltage drop is experienced. However, if the ratio of conductor length to rise distance is large enough, signal reflections from a mismatched load impedance may be received back at the source after the pulse has reached its maximum plateau value, and pulse additions that occur under these circumstances may lead to false triggering of a device. On the other hand, signal attenuation can result in missed signals. One of the causes of signal attenuation is dielectric loss. As the circuit operates, the dielectric medium absorbs energy from the signal. Attenuation of the signal by the dielectric is directly proportional to the square root of permittivity and directly proportional to the loss tangent. In addition, dielectric

PRI PRINT_BIN (VALUE, DIGITS) 'for printing values in BINARY format VALUE <<= 32 - DIGITS '32 digits is the max for our system REPEAT DIGITS 'Repeat for digits desired SEND_CHAR((VALUE <-= 1) & 1 + "0") 'send a 1 or a 0 {this blank line ends this method}